Home Chemistry Classification of Elements and Periodicity JEE Main 2025 Given below are two statements: Statement I:…
Chemistry Classification of Elements and Periodicity JEE Main 2025 Single Correct MCQ
Published on: August 14, 2026

Given below are two statements:

Statement I: is more acidic than
Statement II: has higher bond enthalpy for dissociation than

In the light of the above statements, choose the correct answer from the options given below:

A
Both Statement I and Statement II are true
B
Statement I is true but Statement II is false
C
Both Statement I and Statement II are false
D
Statement I is false but Statement II is true

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Text Solution

Verified by Experts
The correct answer is:
D

To determine the relative acidity and bond enthalpy of and , let's examine both:

Acidic Strength:

The acidity of hydrides increases as we move down the group in the periodic table. This is because the bond strength between hydrogen and the central atom decreases, making it easier for the hydrogen ions to dissociate. Therefore, , being further down the group than , is more acidic:

Bond Enthalpy:

Bond enthalpy refers to the energy required to dissociate a bond. The bond enthalpy decreases down the group due to weaker bonds forming as the atomic size increases.
Hence, has a higher bond enthalpy compared to :

Thus, is indeed less acidic than , but it has a higher bond enthalpy for dissociation.

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